Agreed regarding the ol' sniff test...
And the second part about sanding allowing the remaining solvent to escape, I discovered this as a result of my impatience getting the better of me. I thought it was my imagination or coincidence until Simon mentioned it here a while ago.
I had a body I had sprayed with acrylic lacquer that was taking forever to gas off. I eventually said "stuff it" proceeded with some sanding thinking worst case is I'd have to re-spray it. Within a couple of days after sanding, the solvent odour dropped dramatically and the feel of the lacquer changed (hardened).